Achievement of visible-light-driven Z-scheme overall water splitting using barium-modified Ta3N5 as a H2-evolving photocatalyst.

Achievement of visible-light-driven Z-scheme overall water splitting using barium-modified Ta3N5 as a H2-evolving photocatalyst† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc02750d Click here for additional data file.

Visible light-induced water splitting in an aqueous suspension of a plasmonic Au/TiO2 photocatalyst with metal co-catalysts.

We found that plasmonic Au particles on titanium(iv) oxide (TiO2) act as a visible-light-driven photocatalyst for overall water splitting free from any additives. This is the first report showing that surface plasmon resonance (SPR) in a suspension system effectively induces overall water splitting. Modification with various types of metal nanoparticles as co-catalysts enhanced the evolution of...

Photocatalytic overall water splitting on the perovskite-type transition metal oxynitride CaTaO2N under visible light irradiation.

Overall water splitting was achieved on a simple perovskite oxynitride photocatalyst, CaTaO2N, with an absorption edge at 510 nm. This photocatalyst, modified with a Rh-Cr bimetallic oxide cocatalyst, produced stoichiometric H2 and O2 steadily under UV and visible light irradiation after coating of the photocatalyst particles with amorphous Ti oxyhydroxide.

Photocatalytic CO2 reduction using water as an electron donor by a powdered Z-scheme system consisting of metal sulfide and an RGO-TiO2 composite.

CuGaS2, (AgInS2)x-(ZnS)2-2x, Ag2ZnGeS4, Ni- or Pb-doped ZnS, (ZnS)0.9-(CuCl)0.1, and ZnGa0.5In1.5S4 showed activities for CO2 reduction to form CO and/or HCOOH in an aqueous solution containing K2SO3 and Na2S as electron donors under visible light irradiation. Among them, CuGaS2 and Ni-doped ZnS photocatalysts showed relatively high activities for CO and HCOOH formation, respectively. CuGaS2 wa...

Synthesis of Ta3N5 Nanotube Arrays Modified with Electrocatalysts for Photoelectrochemical Water Oxidation

Tantalum nitride (Ta3N5) is a promising material for photoelectrochemical (PEC) water oxidation with a narrow band gap (2.1 eV) that can effectively utilize visible light in the solar spectrum. Ta3N5 nanotube (NT) arrays were synthesized on a Ta foil by electrochemical anodization followed by an ammonia treatment at 800 °C. The photocurrent of nanostructured Ta3N5 was over 3 times higher than t...